The contribution of Zn(II) and phosphate anions to the inhibition of organic coating cathodic disbondment on galvanised steel by zinc phosphate pigment

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چکیده

In-situ scanning Kelvin probe (SKP) measurements are used to investigate the relative contributions of in-coating zinc (II) cations and phosphate anions inhibition corrosion-driven cathodic disbondment by (ZnPhos) pigments. Using hot-dip galvanized steel (HDG) substrates, delamination rates model polyvinylbutyral (PVB) coatings comprising different pigment volume fractions (?) phosphate-loaded hydrotalcite Zn(II)-exchanged bentonite compared with those established in presence ZnPhos. The most powerful inhibitory effect is obtained using Zn 2+ , while ZnPhos pigments inhibit rather weakly as such principal function control solubility. • Inhibition Zinc investigated on PVB coated HDG. Comparison efficiency separate PO 4 3 ? ion-exchange Powerful influence but far less effective. Principal

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AN IMPROVEMENT TO THE ANTICORROSIVE PROPERTIES OF EPOXY POWDER COATING BY ZINC PHOSPHATE AND ZINC ALUMINUM PHOSPHATE PIGMENTS

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ژورنال

عنوان ژورنال: Corrosion Science

سال: 2022

ISSN: ['1879-0496', '0010-938X']

DOI: https://doi.org/10.1016/j.corsci.2022.110111